Berkeleytrione

Berkeleytrione

Names
IUPAC name Methyl (1R,2S,9R,10S,11R,13R,15S)-9,15-dihydroxy-2,6,6,10,13,15-hexamethyl-17-methylene-7,14,16-trioxotetracyclo[11.3.1.0^2,11.0^5,10]heptadec-4-ene-1-carboxylate
Identifiers
3D model (Jmol)	Interactive image
ChemSpider	10193090
PubChem	21580418
InChI InChI=1S/C26H34O7/c1-13-22(4)12-15-23(5,26(13,20(31)33-8)19(30)25(7,32)18(22)29)10-9-14-21(2,3)16(27)11-17(28)24(14,15)6/h9,15,17,28,32H,1,10-12H2,2-8H3/t15-,17-,22-,23+,24-,25+,26+/m1/s1 Key: BNDPVNXDSQOTOY-OKCDOLPESA-N InChI=1/C26H34O7/c1-13-22(4)12-15-23(5,26(13,20(31)33-8)19(30)25(7,32)18(22)29)10-9-14-21(2,3)16(27)11-17(28)24(14,15)6/h9,15,17,28,32H,1,10-12H2,2-8H3/t15-,17-,22-,23+,24-,25+,26+/m1/s1 Key: BNDPVNXDSQOTOY-OKCDOLPEBK
SMILES C[C@]12CC=C3[C@]([C@@H]1C[C@@]4(C(=C)[C@]2(C(=O)[C@@](C4=O)(C)O)C(=O)OC)C)([C@@H](CC(=O)C3(C)C)O)C
Properties
Chemical formula	C26H34O7
Molar mass	458.55 g·mol^−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Berkeleytrione is a bio-active fungal isolate from the Berkeley Pit.^[1]

References

1. Stierle, DB; Stierle, AA; Hobbs, JD; Stokken, J; Clardy, J (2004). "Berkeleydione and berkeleytrione, new bioactive metabolites from an acid mine organism". Organic Letters. 6 (6): 1049–52. doi:10.1021/ol049852k. PMID 15012097.