Chlorobis(cyclooctene)iridium dimer
 | |
| Identifiers | |
|---|---|
| 12246-51-4 | |
| ECHA InfoCard | 100.159.657 |
| Properties | |
| C32H56Cl2Ir2 | |
| Molar mass | 896.13 |
| Appearance | yellow solid |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Chlorobis(cyclooctene)iridium dimer is an organoiridium compound with the formula Ir2Cl2(C8H14)4, where C8H14 is cis-cyclooctene. Sometimes abbreviated Ir2Cl2(coe)4, it is a yellow, air-sensitive solid that is used as a precursor to many other organoiridium compounds and catalysts.
The compound is prepared by heating an alcohol solution of sodium hexachloroiridate with cyclooctene in ethanol.[1] The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene iridium chloride dimer.
References
- ↑ Van der Ent, A.; Onderdelinden, A. L. "Chlorobis(cyclooctene)rhodium(I) and di-μ-chlorobis[bis(cryclooctene)iridium] (I) complexes" Inorganic Syntheses 1973, volume 14, pp. 92-5. doi:10.1002/9780470132456.ch18
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