Decrespignyite-(Y)

Decrespignyite-(Y)
Near perfect formation of (blue) Decrespignyite-(Y) crystals creating botryoidal type formations with a small amount of (grey) Kamphaugite-(Y)
General
Category	Carbonate minerals
Formula (repeating unit)	Cu(Y, REE)4(CO3)4(OH)5Cl · 2H2O
Strunz classification	5.CC.35
Dana classification	16a.1.11.1
Crystal system	Monoclinic Unknown space group
Identification
Color	bright royal blue to pale blue
Fracture	none observed
Mohs scale hardness	4
Luster	vitreous, pearly
Streak	pale blue
Density	3.64 g/cm3 (measured) 3.645 g/cm3 (calculated)[1]
References	[2][3]

Decrespignyite-(Y) is a copper yttrium rare earth carbonate chloride hydrate;^[1]

With a simple formula of; Cu(Y, REE)₄(CO₃)₄(OH)₅Cl · 2H₂O^[2]

Usually found as single pseudohexagonal platelets, often curved, and regularly measuring 10-50μm in size. It appears as royal blue to turquoise blue in colour, with a pale blue streak, and a pearly to vitreous lustre. Regarded as a supergene mineral which is believed to be formed through by mildly carbonated ground waters precipitating through the ore body. It is often associated with malachite, kamphaugite-(Y), donnayite-(Y) and caysichite-(Y)^[1]

Discovery

First discovered at the Paratoo copper mine, near Yunta, Olary district, South Australia; Decrespignyite-(Y) was first brought to the attention of Dr. Allan Pring (Principal Research Scientist and Head, Mineral Sciences, South Australian Museum 1984^[4]-2015) in 1998, by Mr. John Toma, a prominent South Australian mineral collector and amateur mineralogist. Mr. Toma had noted unusual properties of an unknown mineral specimen, requesting Dr. Pring and the SA museum Mineral Sciences team test the unknown sample.

Research and Publication

Dr. Pring joined with Dr. U. Kolitsch (Curator of minerals and deposit collection, Mineralogical-petrographic Abt. Natural History Museum, Austria), K. Wallwork (School of Chemistry, Physics and Earth Sciences, The Flinders University of South Australia), and L. Nasdala (Institute of Geosciences and Mineralogy, Johannes Gutenberg University, Germany),^[1] to perform the required tests and analyses in order to determine the nature, and properties of this (then) new mineral. Using a combination of X-ray diffraction, with analysis using a 100 mm diameter Guinier-Ha gg camera (using Cr-Kα₁ radiation (l=2.28970 A°) and Si as an internal standard), vibrational spectroscopy gaining Raman spectra obtained by use of a Renishaw RM 1000 system, (equipped with Leica DMLM series optical microscope), and chemical analysis via electron microprobe using a Cameca CAMEBAX SX51 electron microscope, and observations of physical properties; the team eventually determined no other known mineral matched the specimens collected.^[1]

Naming

Results of the analyses were presented to IMA Commission on New Minerals and Mineral Names (2001-027) during 2001. The presentation requested the naming of the new mineral to be made in honour of Australian Mr. Robert J. Champion de Crespigny (b.1950), for recognition of his contributions to the Australian education and the Australian mining industry. At the time he held positions of executive chairman of Normandy Mining Limited, Chancellor of the University of Adelaide, and was the Chairman of the South Australian Museum. The IMA approved the naming, and the status of the mineral Decrespignyite-(Y) (2001-027)^[5] during 2001, with the description paper by Wallwork et al. being published later in 2002.^[1]

References

1. K. Wallwork, U. Kolitsch, A. Pring and L. Nasdala (2002). "Decrespignyite-(Y), a new copper yttrium rare earth carbonate chloride hydrate from Paratoo, South Australia" (PDF). RRUFF. RRUFF. Retrieved October 9, 2015.
2. "Decrespignyite-(Y)". Mindat.org. Mindat. Retrieved October 9, 2015.
3. Webmineral data
4. "Allan Pring". South Australian Museum. South Australian Museum. Retrieved October 9, 2015.
5. "New Minerals Approved In 2001" (PDF). IMA. IMA. Retrieved October 10, 2015.