Jeffrey S. Moore

Jeffrey S. Moore
Born	1962 Joliet, Illinois
Nationality	American
Fields	Organic chemistry, Materials science & Engineering
Institutions	University of Illinois at Urbana-Champaign
Alma mater	University of Illinois at Urbana-Champaign
Doctoral advisor	Samuel I. Stupp
Known for	Self-healing material, Mechanochemistry, and Macromolecular architectures
Website http://sulfur.scs.uiuc.edu/index.html

External video

Jeffrey Moore “College Coaching for Training 21st Century Minds”, TEDxUIUC

Jeffrey Scott Moore (born 1962, Joliet, Illinois)^[1] is the Murchison-Mallory Professor of Chemistry and a Professor of Materials Science & Engineering at the University of Illinois at Urbana-Champaign.^[2] He has received awards for both teaching and research, and as of 2014, was named a Howard Hughes Medical Institute Professor.^[3] As of 2016, he became the Interim Director of the Beckman Institute for Advanced Science and Technology at the University of Illinois.^[4]

Early life and education

Jeffrey Scott Moore was born in 1962 near Joliet, Illinois.^[5] He was awarded his B.S. in chemistry in 1984 and his Ph.D. in Materials Science and Engineering in 1989, both from the University of Illinois.^[1] At Illinois, he worked with Samuel I. Stupp on the molecular organization of polymers,^[6] and developed a new room temperature technique for the polyesterification of high molecular weight polyesters.^[7]

Career

After briefly working as an NSF postdoctoral fellow at the California Institute of Technology with Robert H. Grubbs,^[8] Moore joined the chemistry faculty at the University of Michigan in Ann Arbor, Michigan in 1990.^[1]

In 1993 Moore returned to the University of Illinois as one of the chemistry faculty. He is currently a professor of materials science and engineering, and holds the title of Murchison-Mallory Chair in the Department of Chemistry.^[9] He is a member of the Frederick Seitz Materials Research Laboratory,^[10] and in 1994, he became a part-time faculty member at the Beckman Institute for Advanced Science and Technology, both at the University of Illinois. He is a member of the Autonomous Materials Systems Group, and has served as co-chair of the Institute's Molecular and Electronic Nanostructures theme.^[9]

As a teacher, Moore has developed innovative approaches to large enrollment courses in organic chemistry at the university, integrating online resources, webcasts, and Web-based conferencing to encourage curiosity-driven learning, student participation, autonomy, and problem solving.^[11][12][13] Moore has served as Faculty Advisor to the University of Illinois’ Society of Postdoctoral Scholars since January 2011.^[14] He is credited with "changing the national conversation about how students should learn and about what constitutes an optimum educational environment."^[3]

"He restructured his course so that he could incorporate challenging, open-ended problems that students work through together, with coaching from Moore and other mentors. ... As they attack complex, real-world problems, students learn to take calculated risks, work through uncertainty, and persevere despite setbacks.^[11]

Moore served as interim head of the Department of Chemistry at the University of Illinois from 2012-2013.^[9] He was named a Howard Hughes Medical Institute Professor in 2014.^[3] He became the Interim Director of the Beckman Institute for Advanced Science and Technology in April 2016.^[4] Moore replaced Arthur F. Kramer, who became the new senior vice provost for research at Northeastern University.^[15]

Research

Drawing upon physical organic chemistry and materials science, Moore's group of researchers at the University of Illinois studies the synthesis of large organic molecules and seeks to discover new polymers.^[16] Some of Moore's early work utilized the phenylacetylene moiety in the construction of nanoscale structures such as macrocycles and dendrimers.^[17] He has extensively studied macromolecular architectures,^[18][19] the molecular construction of structures such as foldamers,^[20][21] and the synthesis of shape-persistent macrocycles.^[22]

Understanding the ways in which polymers undergo chemical reactions and produce chemical signals has made it possible to design polymers that can respond to mechanical activation. One of Moore's goals is to engineer mechanically responsive materials that will be safer and last longer than current materials. Working with colleagues such as Nancy Sottos and Scott White, he has developed self-healing polymeric materials. Moore has shown that microencapsulated healing agents can polymerize to heal areas of damage such as cracks smaller than a human hair.^{[10][12][23][24]}

Responsive materials can also be designed to change in response to indicators such as high stress, to signal that problems such as cracks are in danger of developing. Moore's team has developed sensors that can detect and respond to mechanical force. For example, a molecular probe can undergo a color change to signal possible damage.^[12] In 2005, Moore, Jennifer Lewis and others demonstrated a light-sensitive monolayer that could be used to design colloidal fluids, gels and crystals whose surface charge and chemical structure would change depending on their exposure to ultraviolet light.^[25][26][27] More recently Moore and others have created heat-sensitive microspheres that react to conditions such as thermal runaway in Lithium-ion batteries.^[28]

Moore, Sottos and White have demonstrated a novel mechanochemical approach to the manipulation of matter by using mechanical force to bias reaction pathways and prioritize certain chemical transformations over others in chemical reactions.^[12][29] This approach enables scientists to create products that would be impossible to obtain under conventional conditions.^[10]

As of 2014, Moore's team demonstrated a two-stage process that would enable larger areas of damage, on the order of a bullet hole, to be regenerated. The responsive material initially creates a scaffold which is then filled in through secondary chemical reactions.^[12][30]

Moore has been a principal investigator (PI) or co-PI for a number of federal and corporate grants, often working with colleagues across disciplines.^{[28][31][32][33]} In 2007, as PI of "Mechanochemically-Active Polymer Composites", he was one of the winners of a Multi-University Research Initiative (MURI) grant competition from the Department of Defense.^[34]

As of 2012, Moore became the lead investigator for a multi-institutional project working with the Department of Energy (DOE) Joint Center for Energy Storage Research (JCESR) on batteries and energy storage. The Argonne National Laboratory will collaborate with universities and private firms to develop next-generation battery and energy storage technologies, suitable for use in electric and hybrid cars and for storage in the electricity grid. Moore's group is studying redox-active molecules and macromolecules so as to develop macromolecular designs for non-aqueous redox flow battery systems.^[35][36][37]

Jeffrey S. Moore has published over 300 articles in journals such as Macromolecules, the Journal of Chemical Education, Advanced Materials and the Journal of Materials Chemistry.^[4] He served as an Associate Editor for the Journal of the American Chemical Society from July 1999 to 2013.^[38]

Awards and honors

He has been elected as a Fellow of the Royal Society of Chemistry, the American Association for the Advancement of Science,^[39] and the American Academy of Arts and Sciences (2008).^[10] He is a Fellow of the American Chemical Society (ACS, 2010)^[40][41] and of the division of Polymeric Materials: Science and Engineering (PMSE) of the ACS (2010).^[1][5]

His awards include an Alfred P. Sloan Fellowship (1997),^[42] an Arthur C. Cope Scholar Award (1996),^[43] and an NSF Young Investigator Award (1992).^[18]

In 2014, Moore was named a Howard Hughes Medical Institute Professor.^[3] In 2015 he received a Leete Award from the American Chemical Society Division of Organic Chemistry for "outstanding contributions to teaching and research in organic chemistry".^[44][45][46]

Moore has received the Campus Award for Excellence in Undergraduate Teaching,^[12] the Liberal Arts & Sciences Dean’s Award for Excellence in Undergraduate Teaching,^[31] and a Dreyfus Teacher-Scholar Award (1994).^[47] He is one of Illinois' “Faculty Ranked Excellent by their Students”.^[12]

Selected bibliography

Self-healing materials

• White, S. R.; Sottos, N. R.; Geubelle, P. H.; Moore, J. S.; Kessler, M. R.; Sriram, S. R.; Brown, E. N.; Viswanathan, S. (15 February 2001). "Autonomic healing of polymer composites". Nature. 409 (6822): 794–797. doi:10.1038/35057232.
• Toohey, Kathleen S.; Sottos, Nancy R.; Lewis, Jennifer A.; Moore, Jeffrey S.; White, Scott R. (10 June 2007). "Self-healing materials with microvascular networks". Nature Materials. 6 (8): 581–585. doi:10.1038/nmat1934.
• Caruso, Mary M.; Blaiszik, Benjamin J.; White, Scott R.; Sottos, Nancy R.; Moore, Jeffrey S. (9 July 2008). "Full Recovery of Fracture Toughness Using a Nontoxic Solvent‐Based Self‐Healing System" (PDF). Advanced Functional Materials. 18 (13): 1898–1904. doi:10.1002/adfm.200800300.
• Wilson, Gerald O.; Henderson, James W.; Caruso, Mary M.; Blaiszik, Benjamin J.; McIntire, Patrick J.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (15 June 2010). "Evaluation of peroxide initiators for radical polymerization-based self-healing applications" (PDF). Journal of Polymer Science Part A: Polymer Chemistry. 48 (12): 2698–2708. doi:10.1002/pola.24053.
• Esser-Kahn, Aaron P.; Thakre, Piyush R.; Dong, Hefei; Patrick, Jason F.; Vlasko-Vlasov, Vitalii K.; Sottos, Nancy R.; Moore, Jeffrey S.; White, Scott R. (23 August 2011). "Three-Dimensional Microvascular Fiber-Reinforced Composites" (PDF). Advanced Materials. 23 (32): 3654–3658. doi:10.1002/adma.201100933.
• White, S. R.; Moore, J. S.; Sottos, N. R.; Krull, B. P.; Santa Cruz, W. A.; Gergely, R. C. R. (8 May 2014). "Restoration of Large Damage Volumes in Polymers". Science. 344 (6184): 620–623. doi:10.1126/science.1251135. PMID 24812399.

Mechanochemistry

• Hickenboth, Charles R.; Moore, Jeffrey S.; White, Scott R.; Sottos, Nancy R.; Baudry, Jerome; Wilson, Scott R. (22 March 2007). "Biasing reaction pathways with mechanical force". Nature. 446 (7134): 423–427. doi:10.1038/nature05681.
• Davis, Douglas A.; Hamilton, Andrew; Yang, Jinglei; Cremar, Lee D.; Van Gough, Dara; Potisek, Stephanie L.; Ong, Mitchell T.; Braun, Paul V.; Martínez, Todd J.; White, Scott R.; Moore, Jeffrey S.; Sottos, Nancy R. (7 May 2009). "Force-induced activation of covalent bonds in mechanoresponsive polymeric materials". Nature. 459 (7243): 68–72. doi:10.1038/nature07970.
• Caruso, Mary M.; Davis, Douglas A.; Shen, Qilong; Odom, Susan A.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (11 November 2009). "Mechanically-Induced Chemical Changes in Polymeric Materials" (PDF). Chemical Reviews. 109 (11): 5755–5798. doi:10.1021/cr9001353.
• Lee, Corissa K.; Davis, Douglas A.; White, Scott R.; Moore, Jeffrey S.; Sottos, Nancy R.; Braun, Paul V. (17 November 2010). "Force-Induced Redistribution of a Chemical Equilibrium" (PDF). Journal of the American Chemical Society. 132 (45): 16107–16111. doi:10.1021/ja106332g.
• Kryger, Matthew J.; Munaretto, Alexander M.; Moore, Jeffrey S. (23 November 2011). "Structure–Mechanochemical Activity Relationships for Cyclobutane Mechanophores". Journal of the American Chemical Society. 133 (46): 18992–18998. doi:10.1021/ja2086728.
• Diesendruck, Charles E.; Steinberg, Brian D.; Sugai, Naoto; Silberstein, Meredith N.; Sottos, Nancy R.; White, Scott R.; Braun, Paul V.; Moore, Jeffrey S. (August 2012). "Proton-Coupled Mechanochemical Transduction: A Mechanogenerated Acid" (PDF). Journal of the American Chemical Society. 134 (30): 12446–12449. doi:10.1021/ja305645x.
• Robb, Maxwell J.; Moore, Jeffrey S. (21 August 2015). "A Retro-Staudinger Cycloaddition: Mechanochemical Cycloelimination of a β-Lactam Mechanophore". Journal of the American Chemical Society. 137 (34): 10946–10949. doi:10.1021/jacs.5b07345.

Macromolecular architectures

• Ghosh, Koushik; Moore, Jeffrey S. (14 December 2011). "Foldamer Structuring by Covalently Bound Macromolecules". Journal of the American Chemical Society. 133 (49): 19650–19652. doi:10.1021/ja2087163.
• Finke, Aaron D.; Gross, Dustin E.; Han, Amy; Moore, Jeffrey S. (7 September 2011). "Engineering Solid-State Morphologies in Carbazole–Ethynylene Macrocycles". Journal of the American Chemical Society. 133 (35): 14063–14070. doi:10.1021/ja204795q.
• Elliott, Erin L.; Hartley, C. Scott; Moore, Jeffrey S. (2011). "Covalent ladder formation becomes kinetically trapped beyond four rungs". Chemical Communications. 47 (17): 5028. doi:10.1039/C1CC11242B.
• Gross, Dustin E.; Moore, Jeffrey S. (24 May 2011). "Arylene–Ethynylene Macrocycles via Depolymerization–Macrocyclization". Macromolecules. 44 (10): 3685–3687. doi:10.1021/ma2006552.
• Sisco, Scott W.; Moore, Jeffrey S. (6 June 2012). "Directional Cyclooligomers via Alkyne Metathesis". Journal of the American Chemical Society. 134 (22): 9114–9117. doi:10.1021/ja303572k.

Energy storage materials

• Blaiszik, Benjamin J.; Kramer, Sharlotte L. B.; Grady, Martha E.; McIlroy, David A.; Moore, Jeffrey S.; Sottos, Nancy R.; White, Scott R. (17 January 2012). "Autonomic Restoration of Electrical Conductivity" (PDF). Advanced Materials. 24 (3): 398–401. doi:10.1002/adma.201102888.
• Esser-Kahn, Aaron P.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (4 August 2010). "Programmable Microcapsules from Self-Immolative Polymers" (PDF). Journal of the American Chemical Society. 132 (30): 10266–10268. doi:10.1021/ja104812p.
• Odom, Susan A.; Tyler, Timothy P.; Caruso, Mary M.; Ritchey, Joshua A.; Schulmerich, Matthew V.; Robinson, Scott J.; Bhargava, Rohit; Sottos, Nancy R.; White, Scott R.; Hersam, Mark C.; Moore, Jeffrey S. (2012). "Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules" (PDF). Applied Physics Letters. 101 (4): 043106. doi:10.1063/1.4737935.
• Odom, Susan A.; Chayanupatkul, Sarut; Blaiszik, Benjamin J.; Zhao, Ou; Jackson, Aaron C.; Braun, Paul V.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (15 May 2012). "A Self-healing Conductive Ink" (PDF). Advanced Materials. 24 (19): 2578–2581. doi:10.1002/adma.201200196.
• Baginska, Marta; Blaiszik, Benjamin J.; Merriman, Ryan J.; Sottos, Nancy R.; Moore, Jeffrey S.; White, Scott R. (May 2012). "Autonomic Shutdown of Lithium-Ion Batteries Using Thermoresponsive Microspheres" (PDF). Advanced Energy Materials. 2 (5): 583–590. doi:10.1002/aenm.201100683.
• Blaiszik, Benjamin J.; Kramer, Sharlotte L. B.; Grady, Martha E.; McIlroy, David A.; Moore, Jeffrey S.; Sottos, Nancy R.; White, Scott R. (17 January 2012). "Autonomic Restoration of Electrical Conductivity" (PDF). Advanced Materials. 24 (3): 398–401. doi:10.1002/adma.201102888.

References

1. "Tenth Class of PMSE Fellows" (PDF). PMSE News (Fall). 2010. Retrieved 9 June 2016.
2. "Prof. Jeffrey S. Moore". University of Illinois. Retrieved 9 June 2016.
3. Ahlberg, Liz (June 30, 2014). "Illinois chemist named Howard Hughes Medical Institute Professor". Illinois News Bureau. Retrieved 9 June 2016.
4. "Moore Named Interim Director". Beckman Institute. April 1, 2016. Retrieved 9 June 2016.
5. "2010 PMSE Fellows". Polymeric Materials: Science and Engineering Division. American Chemical Society. Retrieved 9 June 2016.
6. Moore, J. S.; Stupp, S. I. (March 1987). "Orientation dynamics of main-chain liquid crystal polymers. 2. Structure and kinetics in a magnetic field". Macromolecules. 20 (2): 282–293. doi:10.1021/ma00168a009. Retrieved 9 June 2016.
7. Moore, Jeffrey S.; Stupp, Samuel I. (January 1990). "Room temperature polyesterification". Macromolecules. 23 (1): 65–70. doi:10.1021/ma00203a013. Retrieved 9 June 2016.
8. "Jeffrey Scott Moore". Chemistry Tree. Retrieved 9 June 2016.
9. Wurth, Julie (April 1, 2016). "Interim leader chosen for Beckman". The News-Gazette. Retrieved 9 June 2016.
10. "Moore elected to American Academy of Arts and Sciences". Chemistry at Illinois. Retrieved 9 June 2016.
11. Ahlberg, Liz (July 1, 2014). "Illinois Chemist named Howard Hughes Medical Institute Professor". Carl R. Woese Institute for Genomic Biology. Retrieved 9 June 2016.
12. "Jeffrey S. Moore, PhD HHMI Professor / 2014–Present / Biography". Howard Hughes Medical Institute. Retrieved 9 June 2016.
13. "The Molecular Sciences Made Personal". Howard Hughes Medical Institute. Retrieved 10 June 2016.
14. "Who We Are". Society of Postdoctoral Scholars. University of Illinois at Urbana-Champaign. Retrieved 9 June 2016.
15. St. Martin, Greg (January 6, 2016). "Northeastern appoints new senior vice provost for research". News @ Northeastern. Retrieved 9 June 2016.
16. "The Moore Group". University of Illinois. Retrieved 10 June 2016.
17. Young, James K.; Nelson, James C.; Moore, Jeffrey S. (November 1994). "Synthesis of Sequence Specific Phenylacetylene Oligomers on an Insoluble Solid Support". Journal of the American Chemical Society. 116 (23): 10841–10842. doi:10.1021/ja00102a082. Retrieved 10 June 2016.
18. DRDA Reporter. Ann Arbor: The Division of Research Development and Administration, University of Michigan. 1992. p. 14. Retrieved 9 June 2016.
19. Young, James K.; Moore, Jeffrey S. (1995). "Chapter 12: Acetylenes in nanostructures". In Stang, P.J.; Diederich, F. Modern acetylene chemistry. Weinheim: VCH. pp. 415–418. ISBN 9783527290840.
20. Hill, David J.; Mio, Matthew J.; Prince, Ryan B.; Hughes, Thomas S.; Moore, Jeffrey S. (December 2001). "A Field Guide to Foldamers". Chemical Reviews. 101 (12): 3893–4012. doi:10.1021/cr990120t. Retrieved 10 June 2016.
21. Jamison, Christophier. "Highlights from the career of Jeffrey S. Moore" (PDF). Princeton University. Retrieved January 31, 2013.
22. Zhang, Wei; Moore, Jeffrey S. (3 July 2006). "Shape-Persistent Macrocycles: Structures and Synthetic Approaches from Arylene and Ethynylene Building Blocks". Angewandte Chemie International Edition. 45 (27): 4416–4439. doi:10.1002/anie.200503988. Retrieved 10 June 2016.
23. McGaughey, Steve (October 17, 2007). "Team Approach Pays Off Big for Moore". Beckman Institute. University of Illinois. Retrieved 10 June 2016.
24. Toohey, Kathleen S.; Sottos, Nancy R.; Lewis, Jennifer A.; Moore, Jeffrey S.; White, Scott R. (10 June 2007). "Self-healing materials with microvascular networks". Nature Materials. 6 (8): 581–585. doi:10.1038/nmat1934.
25. Kloeppel, James E. (March 27, 2006). "Light-sensitive particles change chemistry at the flick of a switch". Illinois News Bureau. Retrieved 10 June 2016.
26. Plunkett, Kyle N.; Mohraz, Ali; Haasch, Richard T.; Lewis, Jennifer A.; Moore, Jeffrey S. (October 2005). "Light-Regulated Electrostatic Interactions in Colloidal Suspensions" (PDF). Journal of the American Chemical Society. 127 (42): 14574–14575. doi:10.1021/ja054666a. Retrieved 10 June 2016.
27. Davis, Douglas A.; Hamilton, Andrew; Yang, Jinglei; Cremar, Lee D.; Van Gough, Dara; Potisek, Stephanie L.; Ong, Mitchell T.; Braun, Paul V.; Martínez, Todd J.; White, Scott R.; Moore, Jeffrey S.; Sottos, Nancy R. (7 May 2009). "Force-induced activation of covalent bonds in mechanoresponsive polymeric materials". Nature. 459 (7243): 68–72. doi:10.1038/nature07970. Retrieved 10 June 2016.
28. Glynn, Patrick (December 5, 2012). "Preventing Laptop Fires and "Thermal Runaway"". U.S. Department of Energy. Retrieved 10 June 2016.
29. Hickenboth, Charles R.; Moore, Jeffrey S.; White, Scott R.; Sottos, Nancy R.; Baudry, Jerome; Wilson, Scott R. (22 March 2007). "Biasing reaction pathways with mechanical force". Nature. 446 (7134): 423–427. doi:10.1038/nature05681.
30. White, S. R.; Moore, J. S.; Sottos, N. R.; Krull, B. P.; Santa Cruz, W. A.; Gergely, R. C. R. (8 May 2014). "Restoration of Large Damage Volumes in Polymers". Science. 344 (6184): 620–623. doi:10.1126/science.1251135. PMID 24812399.
31. Chemical Sciences Roundtable, Board on Chemical Sciences and Technology, Division on Earth and Life Studies, National Research Council (2014). Undergraduate chemistry education : a workshop summary. National Academies Press. ISBN 978-0-309-29586-4. Retrieved 9 June 2016.
32. "Award Abstract #1300313 Mechanogenerated Acids". National Science Foundation. 2013. Retrieved 10 June 2016.
33. "Award Abstract #1307354 SusChem/FRG/GOALI: Mechanochemically Based Sustainable Polymers". National Science Foundation. 2013. Retrieved 10 June 2016.
34. "Large MURI Grants go to Projects Headed by Beckman Researchers". Beckman Institute. April 20, 2007. Retrieved 10 June 2016.
35. "Illinois partners with DOE, Argonne to establish Batteries and Energy Storage Hub". Engineering at Illinois. December 3, 2012. Retrieved 10 June 2016.
36. Montoto1, Elena C.; Nagarjuna1, Gavvalapalli; Sekerak1, Nina; Kneer, Marissa; Hernandez-Burgos, Kenneth; Moore1, Jeffrey S.; Rodriguez-Lopez, Joaquin (2015). "Macromolecular designs for non-aqueous redox flow battery systems". SACNAS National Conference. Retrieved 10 June 2016.
37. "Energy Storage Materials". The Moore Group. University of Illinois. Retrieved 10 June 2016.
38. "Jeffrey S. Moore". Chemistry at Illinois. Retrieved 10 June 2016.
39. "Fellows of the AAAS" (PDF). American Association for the Advancement of Science. Retrieved 10 June 2016.
40. Ahlberg, Liz (August 4, 2010). "Four University of Illinois professors elected ACS fellows". Illinois News Bureau. Retrieved 9 June 2016.
41. "2010 ACS Fellows". American Chemical Society. Retrieved 9 June 2016.
42. "Past Fellows". Alfred P. Sloan Foundation. Retrieved 9 June 2016.
43. "Arthur C. Cope Scholar Awards". American Chemical Society. Retrieved 9 June 2016.
44. "Awards". Carl R. Woese Institute for Genomic Biology. Retrieved 9 June 2016.
45. "Jeffrey Moore Honored by 2015 Edward Leete Award". Chemistry at Illinois. Retrieved 9 June 2016.
46. "Edward Leete Award". American Chemical Society. Retrieved 9 June 2016.
47. "Camille Dreyfus Teacher-Scholar Awards Program" (PDF). The Camille and Henry Dreyfus Foundation. Retrieved 9 June 2016.

External links

• Moore Group Website