Bromochloromethane
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| Names | |
|---|---|
| Preferred IUPAC name
Bromo(chloro)methane | |
| Other names | |
| Identifiers | |
74-97-5  | |
| 3D model (Jmol) | Interactive image |
| 3DMet | B00481 |
| Abbreviations |
|
| 1730801 | |
| ChEBI | CHEBI:17194 |
| ChEMBL | ChEMBL346918 |
| ChemSpider | 6093 |
| ECHA InfoCard | 100.000.752 |
| EC Number | 200-826-3 |
| 25577 | |
| KEGG | C02661 |
| MeSH | bromochloromethane |
| PubChem | 6333 |
| RTECS number | PA5250000 |
| UN number | 1887 |
| |
| |
| Properties | |
| CH2BrCl | |
| Molar mass | 129.38 g·mol−1 |
| Appearance | Colorless liquid |
| Odor | chloroform-like[1] |
| Density | 1.991 g mL−1 |
| Melting point | −88.0 °C; −126.3 °F; 185.2 K |
| Boiling point | 68 °C; 154 °F; 341 K |
| 16.7 g L−1 | |
| log P | 1.55 |
| Vapor pressure | 15.60 kPa (at 20.0 °C) |
| Refractive index (nD) |
1.482 |
| Hazards | |
| GHS pictograms |   |
| GHS signal word | DANGER |
| H315, H318, H332, H335 | |
| P261, P280, P305+351+338 | |
| EU classification (DSD) |
 Xi  N |
| R-phrases | R37/38, R41, R59 |
| S-phrases | S26, S39 |
| Flash point | noncombustible [1] |
| Lethal dose or concentration (LD, LC): | |
| LD50 (median dose) |
|
| LC50 (median concentration) |
3000 ppm (mouse, 7 hr)[2] |
| LCLo (lowest published) |
28,800 ppm (rat, 15 min) 29,000 ppm (rat, 15 min) 27,000 ppm (mouse, 15 min)[2] |
| US health exposure limits (NIOSH): | |
| PEL (Permissible) |
TWA 200 ppm (1050 mg/m3)[1] |
| REL (Recommended) |
TWA 200 ppm (1050 mg/m3)[1] |
| IDLH (Immediate danger) |
2000 ppm[1] |
| Related compounds | |
| Related alkanes |
|
| Related compounds |
2-Chloroethanol |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify (what is  ?) | |
| Infobox references | |
Bromochloromethane or methylene bromochloride and Halon 1011 is a mixed halomethane. It is a heavy low-viscosity liquid with refractive index 1.4808.
It was invented for use in fire extinguishers by the Germans during the mid-1940s, in an attempt to create a less-toxic, more effective alternative to carbon tetrachloride. This was a concern in aircraft and tanks as carbon tetrachloride produced highly toxic by-products when discharged onto a fire. CBM was slightly less toxic, and used up until the late 1960s, being officially banned by the NFPA for use in fire extinguishers in 1969, as safer and more effective agents such as halon 1211 and 1301 were developed. Due to its ozone depletion potential its production was banned from January 1, 2002, at the Eleventh Meeting of the Parties for the Montreal Protocol on Substances that Deplete the Ozone Layer.
It can be biologically decomposed using the hydrolase enzyme alkylhalidase by the reaction:
In fiction
In the Enter the Matrix video game, the player can find a "Chloro-Bromo Methane Gun", which is used as a fire extinguisher. It fires a pressurized cartridge of CBM gas to put out fires. However, due to its chemical properties, firing a cartridge near people causes their lungs to fill with liquid, effectively drowning them.
References
- 1 2 3 4 5 6 7 8 9 10 "NIOSH Pocket Guide to Chemical Hazards #0123". National Institute for Occupational Safety and Health (NIOSH).
- 1 2 3 "Chlorobromomethane". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).
External links
- International Chemical Safety Card 0392
- "NIOSH Pocket Guide to Chemical Hazards #0123". National Institute for Occupational Safety and Health (NIOSH).
- Notice with Respect to n-Propyl Bromide and Bromochloromethane
- Chemical fact sheet
- Data sheet at albemarle.com