Thallium(III) nitrate

Thallium(III) nitrate

Names
IUPAC name thallium(3+) trinitrate
Identifiers
CAS Number	13746-98-0
3D model (Jmol)	Interactive image
ChemSpider	140409
PubChem	159690
InChI InChI=1S/3NO3.Tl/c3*2-1(3)4;/q3*-1;+3 Key: KLBIUKJOZFWCLW-UHFFFAOYSA-N
SMILES [Tl+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Chemical formula	Tl(NO3)3
Molar mass	390.398
Appearance	colorless solid
Melting point	103 °C (217 °F; 376 K)
Boiling point	decomposes
Solubility in water	decomposes
Hazards
Safety data sheet	Mallinckrodt Baker
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO₃)₃.^[1] It is normally found as the trihydrate. It is a colorless and highly toxic solid. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.^[2]

References

1. MSDS for thallium(III) nitrate
2. Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2

Salts and covalent derivatives of the Nitrate ion
HNO3																	He
LiNO3	Be(NO3)2											B(NO3)4^−	C	N	O	FNO3	Ne
NaNO3	Mg(NO3)2											Al(NO3)3	Si	P	S	ClONO2	Ar
KNO3	Ca(NO3)2	Sc(NO3)3	Ti(NO3)4	VO(NO3)3	Cr(NO3)3	Mn(NO3)2	Fe(NO3)3	Co(NO3)2, Co(NO3)3	Ni(NO3)2	Cu(NO3)2	Zn(NO3)2	Ga(NO3)3	Ge	As	Se	Br	Kr
RbNO3	Sr(NO3)2	Y	Zr(NO3)4	Nb	Mo	Tc	Ru	Rh	Pd(NO3)2	AgNO3	Cd(NO3)2	In	Sn	Sb	Te	I	Xe(NO3)2
CsNO3	Ba(NO3)2		Hf	Ta	W	Re	Os	Ir	Pt	Au	Hg2(NO3)2, Hg(NO3)2	Tl(NO3)3	Pb(NO3)2	Bi(NO3)3 BiO(NO3)	Po	At	Rn
Fr	Ra		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La	Ce(NO3)3, Ce(NO3)4	Pr	Nd	Pm	Sm	Eu	Gd(NO3)3	Tb	Dy	Ho	Er	Tm	Yb	Lu
		Ac	Th	Pa	UO2(NO3)2	Np	Pu	Am	Cm	Bk	Cf	Es	Fm	Md	No	Lr