Trihydroxypterocarpan dimethylallyltransferase

Trihydroxypterocarpan dimethylallyltransferase
Identifiers
EC number	2.5.1.36
CAS number	70851-94-4
Databases
IntEnz	IntEnz view
BRENDA	BRENDA entry
ExPASy	NiceZyme view
KEGG	KEGG entry
MetaCyc	metabolic pathway
PRIAM	profile
PDB structures	RCSB PDB PDBe PDBsum
Search PMC articles PubMed articles NCBI proteins

Trihydroxypterocarpan dimethylallyltransferase (EC 2.5.1.36, glyceollin synthase, dimethylallylpyrophosphate:3,6a,9-trihydroxypterocarpan dimethylallyltransferase, dimethylallylpyrophosphate:trihydroxypterocarpan dimethylallyl transferase, dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan dimethyltransferase) is an enzyme with systematic name dimethylallyl-diphosphate:(6aS,11aS)-3,6a,9-trihydroxypterocarpan dimethylallyltransferase.^[1][2] This enzyme catalyses the following chemical reaction

(1) dimethylallyl diphosphate + (6aS,11aS)-3,6a,9-trihydroxypterocarpan $\rightleftharpoons$ diphosphate + 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan

(2) dimethylallyl diphosphate + (6aS,11aS)-3,6a,9-trihydroxypterocarpan $\rightleftharpoons$ diphosphate + 4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan

Part of the glyceollin biosynthesis system in soy bean.

References

1. Leube, J.; Grisebach, H. (1983). "Further studies on induction of enzymes of phytoalexin synthesis in soybean and cultured soybean cells". Z. Naturforsch. C: Biosci. 38: 730–735.
2. Zähringer, U.; Schaller, E.; Grisebach, H. (1981). "Induction of phytoalexin synthesis in soybean. Structure and reactions of naturally occurring and enzymatically prepared prenylated pterocarpans from elicitor-treated cotyledons and cell cultures of soybean". Z. Naturforsch. C. 36: 234–241.

External links

• Trihydroxypterocarpan dimethylallyltransferase at the US National Library of Medicine Medical Subject Headings (MeSH)