(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

Identifiers
CAS Number	72287-26-4 95464-05-4 complex with DCM
ChemSpider	24602493
ECHA InfoCard	100.106.747
InChI InChI=1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2 Key: JCWIWBWXCVGEAN-UHFFFAOYSA-L
Properties
Chemical formula	C34H28Cl2FeP2Pd
Molar mass	731.71 g·mol^−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is an palladium complex containing the iron-containing dppf ligand. Commercially available, this compound is popularly used for palladium-catalyzed coupling reactions.

Commercially available, this compound may be prepared from dppf and nitrile complexes of palladium dichloride:^[1]

dppf + PdCl₂(RCN)₂ → (dppf)PdCl₂ + 2 RCN (RCN = acetonitrile or benzonitrile)

References

1. Nataro, Chip; Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1'-Bis(diphenylphosphino)ferrocene". J. Chem. Ed. 86: 1412. doi:10.1021/ed086p1412.