Yttrium barium copper oxide

Yttrium barium copper oxide
Names
IUPAC name
barium copper yttrium oxide
Other names
YBCO, Y123, yttrium barium cuprate
Identifiers
107539-20-8 YesY
ECHA InfoCard 100.121.379
Properties
YBa2Cu3O7
Molar mass 666.19 g/mol
Appearance Black solid
Density 6.3 g/cm3[1][2]
Melting point >1000 °C
Insoluble
Structure
Based on the perovskite structure.
Orthorhombic
Hazards
Irritant (Xi)
Related compounds
La2-xSrxCuO4 (LSCO)
Related compounds
 Yttrium(III) oxide
Barium oxide
Copper(II) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds, famous for displaying "high-temperature superconductivity". It includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen (77 K) at about 90 K. Many YBCO compounds have the general formula YBa2Cu3O7-x (also known as Y123), although materials with other Y:Ba:Cu ratios exist, such as YBa2Cu4Oy (Y124) or Y2Ba4Cu7Oy (Y247).

History

In April 1986, Georg Bednorz and Karl Müller, working at IBM in Zurich, discovered that certain semiconducting oxides became superconducting at relatively high temperature, in particular, a lanthanum barium copper oxide which becomes superconducting at 35 K. This oxide was an oxygen deficient perovskite-related material that proved promising, and stimulated the search for related compounds with higher superconducting transition temperatures. In 1987, Bednorz and Müller were jointly awarded the Nobel Prize in Physics for this work.

Following Bednorz and Müller's work, in 1987 Maw-Kuen Wu and Chu Ching-wu and their graduate students Ashburn and Torng[3] at the University of Alabama in Huntsville, discovered that YBCO has a critical temperature (Tc) of 93 K. (The first samples were Y1.2Ba0.8CuO4.) That paper led to rapid discovery of several new high temperature superconducting materials, ushering in a new era in material science and chemistry.

YBCO was the first material found to become superconducting above 77 K, the boiling point of liquid nitrogen. All materials developed before 1986 became superconducting only at temperatures near the boiling points of liquid helium (Tb = 4.2 K) or liquid hydrogen (Tb = 20.28 K) — the highest being Nb3Ge at 23 K. The significance of the discovery of YBCO is the much lower cost of the refrigerant used to cool the material to below the critical temperature.

Synthesis

Relatively pure YBCO was first synthesized by heating a mixture of the metal carbonates at temperatures between 1000 and 1300 K.[4][5]

4 BaCO3 + Y2(CO3)3 + 6 CuCO3 + (1/2−x) O2 → 2 YBa2Cu3O7−x + 13 CO2

Modern syntheses of YBCO use the corresponding oxides and nitrates.[5]

The superconducting properties of YBa2Cu3O7−x are sensitive to the value of x, its oxygen content. Only those materials with 0 ≤ x ≤ 0.65 are superconducting below Tc, and when x ~ 0.07 the material superconducts at the highest temperature of 95 K,[5] or in highest magnetic fields: 120 T for B perpendicular and 250 T for B parallel to the CuO2 planes.[6]

In addition to being sensitive to the stoichiometry of oxygen, the properties of YBCO are influenced by the crystallization methods used. Care must be taken to sinter YBCO. YBCO is a crystalline material, and the best superconductive properties are obtained when crystal grain boundaries are aligned by careful control of annealing and quenching temperature rates.

Numerous other methods to synthesize YBCO have developed since its discovery by Wu and his coworkers, such as chemical vapor deposition (CVD),[4][5] sol-gel,[7] and aerosol[8] methods. These alternative methods, however, still require careful sintering to produce a quality product.

However, new possibilities have been opened since the discovery that trifluoroacetic acid (TFA), a source of fluorine, prevents the formation of the undesired barium carbonate (BaCO3). Routes such as CSD (chemical solution deposition) have opened a wide range of possibilities, particularly in the preparation of long length YBCO tapes.[9] This route lowers the temperature necessary to get the correct phase to around 700 °C. This, and the lack of dependence on vacuum, makes this method a very promising way to get scalable YBCO tapes.

Structure

Part of the lattice structure of yttrium barium copper oxide

YBCO crystallises in a defect perovskite structure consisting of layers. The boundary of each layer is defined by planes of square planar CuO4 units sharing 4 vertices. The planes can sometimes be slightly puckered.[4] Perpendicular to these CuO2 planes are CuO4 ribbons sharing 2 vertices. The yttrium atoms are found between the CuO2 planes, while the barium atoms are found between the CuO4 ribbons and the CuO2 planes. This structural feature is illustrated in the figure to the right.

More details

Like all superconductors, YBCO displays the Meissner effect. Below its critical temperature, YBCO becomes perfectly diamagnetic and excludes sufficiently weak magnetic fields from passing through it.[4]

Although YBa2Cu3O7 is a well-defined chemical compound with a specific structure and stoichiometry, materials with fewer than seven oxygen atoms per formula unit are non-stoichiometric compounds. The structure of these materials depends on the oxygen content. This non-stoichiometry is denoted by the x in the chemical formula YBa2Cu3O7-x. When x = 1, the O(1) sites in the Cu(1) layer are vacant and the structure is tetragonal. The tetragonal form of YBCO is insulating and does not superconduct. Increasing the oxygen content slightly causes more of the O(1) sites to become occupied. For x < 0.65, Cu-O chains along the b axis of the crystal are formed. Elongation of the b axis changes the structure to orthorhombic, with lattice parameters of a = 3.82, b = 3.89, and c = 11.68 Å. Optimum superconducting properties occur when x ~ 0.07, i.e., almost all of the O(1) sites are occupied, with few vacancies.

In experiments where other elements are substituted on the Cu and Ba sites, evidence has shown that conduction occurs in the Cu(2)O planes while the Cu(1)O(1) chains act as charge reservoirs, which provide carriers to the CuO planes. However, this model fails to address superconductivity in the homologue Pr123 (praseodymium instead of yttrium).[10] This (conduction in the copper planes) confines conductivity to the a-b planes and a large anisotropy in transport properties is observed. Along the c axis, normal conductivity is 10 times smaller than in the a-b plane. For other cuprates in the same general class, the anisotropy is even greater and inter-plane transport is highly restricted.

Furthermore, the superconducting length scales show similar anisotropy, in both penetration depth (λab ≈ 150 nm, λc ≈ 800 nm) and coherence length, (ξab ≈ 2 nm, ξc ≈ 0.4 nm). Although the coherence length in the a-b plane is 5 times greater than that along the c axis it is quite small compared to classic superconductors such as niobium (where ξ ≈ 40 nm). This modest coherence length means that the superconducting state is more susceptible to local disruptions from interfaces or defects on the order of a single unit cell, such as the boundary between twinned crystal domains. This sensitivity to small defects complicates fabricating devices with YBCO, and the material is also sensitive to degradation from humidity.

Applications

YBCO superconductor in TTÜ.

Many possible applications of this and related high temperature superconducting materials have been discussed. For example, superconducting materials are finding use as magnets in magnetic resonance imaging, magnetic levitation, and Josephson junctions. (The most used material for power cables and magnets is BSCCO.)

YBCO has yet to be used in many applications involving superconductors for two primary reasons:

It should be noted that cooling materials to liquid nitrogen temperature (77 K) is often not practical on a large scale, although many commercial magnets are routinely cooled to liquid helium temperatures (4.2 K).

The most promising method developed to utilize this material involves deposition of YBCO on flexible metal tapes coated with buffering metal oxides. This is known as coated conductor. Texture (crystal plane alignment) can be introduced into the metal tape itself (the RABiTS process) or a textured ceramic buffer layer can be deposited, with the aid of an ion beam, on an untextured alloy substrate (the IBAD process). Subsequent oxide layers prevent diffusion of the metal from the tape into the superconductor while transferring the template for texturing the superconducting layer. Novel variants on CVD, PVD, and solution deposition techniques are used to produce long lengths of the final YBCO layer at high rates. Companies pursuing these processes include American Superconductor, Superpower (a division of Furukawa Electric), Sumitomo, Fujikura, Nexans Superconductors, and European Advanced Superconductors. A much larger number of research institutes have also produced YBCO tape by these methods.

The superconducting tape may be the key to a tokamak fusion reactor design that can achieve breakeven energy production.[11] YBCO tape is often referred to as rare-earth barium copper oxide (REBCO) tape.[12]

Surface modification of YBCO

Surface modification of materials has often led to new and improved properties. Corrosion inhibition, polymer adhesion and nucleation, preparation of organic superconductor/insulator/high-Tc superconductor trilayer structures, and the fabrication of metal/insulator/superconductor tunnel junctions have been developed using surface-modified YBCO.[13]

These molecular layered materials are synthesized using cyclic voltammetry. Thus far, YBCO layered with alkylamines, arylamines, and thiols have been produced with varying stability of the molecular layer. It has been proposed that amines act as Lewis bases and bind to Lewis acidic Cu surface sites in YBa2Cu3O7 to form stable coordination bonds.

References

  1. ↑ Knizhnik, A (2003). "Interrelation of preparation conditions, morphology, chemical reactivity and homogeneity of ceramic YBCO". Physica C: Superconductivity. 400: 25. Bibcode:2003PhyC..400...25K. doi:10.1016/S0921-4534(03)01311-X.
  2. ↑ Grekhov, I (1999). "Growth mode study of ultrathin HTSC YBCO films on YBaCuNbO buffer". Physica C: Superconductivity. 324: 39. Bibcode:1999PhyC..324...39G. doi:10.1016/S0921-4534(99)00423-2.
  3. ↑ Wu, M. K.; Ashburn, J. R.; Torng, C. J.; Hor, P. H.; Meng, R. L.; Gao, L; Huang, Z. J.; Wang, Y. Q.; Chu, C. W. (1987). "Superconductivity at 93 K in a New Mixed-Phase Y-Ba-Cu-O Compound System at Ambient Pressure". Physical Review Letters. 58 (9): 908–910. Bibcode:1987PhRvL..58..908W. doi:10.1103/PhysRevLett.58.908. PMID 10035069.
  4. 1 2 3 4 Housecroft, C. E.; Sharpe, A. G. (2004). Inorganic Chemistry (2nd ed.). Prentice Hall. ISBN 978-0130399137.
  5. 1 2 3 4 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
  6. ↑ Sekitani, T.; Miura, N.; Ikeda, S.; Matsuda, Y.H.; Shiohara, Y. (2004). "Upper critical field for optimally-doped YBa2Cu3O7−δ". Physica B: Condensed Matter. 346–347: 319. Bibcode:2004PhyB..346..319S. doi:10.1016/j.physb.2004.01.098.
  7. ↑ Sun, Yang-Kook & Oh, In-Hwan (1996). "Preparation of Ultrafine YBa2Cu3O7−x Superconductor Powders by the Poly(vinyl alcohol)-Assisted Sol−Gel Method". Ind. Eng. Chem. Res. 35 (11): 4296. doi:10.1021/ie950527y.
  8. ↑ Zhou, Derong (1991). "Yttrium Barium Copper Oxide Superconducting Powder Generation by An Aerosol Process" (Ph.D. Thesis). University of Cincinnati: 28. Bibcode:1991PhDT........28Z.
  9. ↑ Casta o, O; Cavallaro, A; Palau, A; Gonz Lez, J C; Rossell, M; Puig, T; Sandiumenge, F; Mestres, N; Pi Ol, S; Pomar, A; Obradors, X (2003). "High quality YBa2Cu3O{7–x} thin films grown by trifluoroacetates metal-organic deposition". Supercond. Sci. Technol. 16: 45–53. Bibcode:2003SuScT..16...45C. doi:10.1088/0953-2048/16/1/309.
  10. ↑ Oka, K (1998). "Crystal growth of superconductive PrBa2Cu3O7−y". Physica C. 300 (3–4): 200. Bibcode:1998PhyC..300..200O. doi:10.1016/S0921-4534(98)00130-0.
  11. ↑ A small, modular, efficient fusion plant | MIT News. Newsoffice.mit.edu. Retrieved on 2015-12-09.
  12. ↑ MIT takes a page from Tony Stark, edges closer to an ARC fusion reactor
  13. ↑ Xu, F.; et al. (1998). "Surface Coordination Chemistry of YBa2Cu3O7-δ". Langmuir. 14 (22): 6505. doi:10.1021/la980143n.
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