Color of water

For the book by James McBride, see The Color of Water.
a glass of transparent water sitting on a wooden table
When water is in small quantities (e.g. in a glass) it appears colorless to the human eye

While relatively small quantities of water appear to be colorless, water's tint becomes a deeper blue as the thickness of the observed sample increases. The blue hue of water is an intrinsic property and is caused by the selective absorption and scattering of white light. Impurities dissolved or suspended in water may give water different colored appearances.

Intrinsic color

For more details on this topic, see Electromagnetic absorption by water.
An indoor swimming pool appears blue from above, as light reflecting from the bottom of the pool travels through enough water that its red component is absorbed. The same water in a smaller bucket looks only slightly blue,[1] and observing the water at close range will make it appear colorless to the human eye.

The intrinsic color of liquid water may be demonstrated by looking at a white light source through a long pipe that is filled with purified water and closed at both ends with a transparent window. The light turquoise blue color is caused by weak absorption in the red part of the visible spectrum.[2][3]

For most substances, absorptions in the visible spectrum are usually attributed to excitations of electronic energy states. However, water is a simple 3-atom molecule, H2O, and all its electronic absorptions occur in the ultraviolet region of the electromagnetic spectrum and are therefore not responsible for the color of water in the visible region of the spectrum. Nevertheless, the water molecule has three fundamental modes of vibration, including two stretching vibrations of the O-H bonds which occur at v1 = 3650 cm−1 and v3 = 3755 cm−1. Absorption due to these vibrations occurs in the infrared region of the spectrum. The absorption in the visible spectrum is due mainly to the harmonic v1 + 3v3 = 14,318 cm−1, which is equivalent to a wavelength of 698 nm.[2]

Absorption intensity decreases markedly with each successive overtone, resulting in very weak absorption for the third overtone. For this reason, the pipe needs to have a length of a meter or more and the water must be purified by microfiltration to remove any particles that could produce Mie scattering.

Color of lakes and oceans

Large bodies of water such as oceans manifest water's inherent slightly blue color

Lakes and oceans appear blue for several reasons. One is that the surface of the water reflects the color of the sky. While this reflection contributes to the observed color, it is not the sole reason.[4]

Some of the light, hitting the surface of ocean, is reflected back directly but most of it penetrates the water surface interacting with its molecules. The water molecule can vibrate in three different modes when light hits it. The red, orange, yellow, and green wavelengths of light are absorbed so that the remaining light we see is composed of the shorter wavelength blues and violets. This is the main reason why ocean color is blue.

Some constituents of sea water can influence the shade of blue of the ocean. This is why it can look greener or bluer in different areas. Water in swimming pools (which may also contain various chemicals) with white-painted sides and bottom will appear as a turquoise blue.

Clean water appears blue in white-tiled swimming pools as well as in indoor pools where there is no blue sky to be reflected. The deeper the pool, the bluer the water.[5]

Scattering from suspended particles also plays an important role in the color of lakes and oceans. A few tens of meters of water will absorb all light, so without scattering, all bodies of water would appear black. Because most lakes and oceans contain suspended living matter and mineral particles, known as colored dissolved organic matter (CDOM), light from above is reflected upwards. Scattering from suspended particles would normally give a white color, as with snow, but because the light first passes through many meters of blue-colored liquid, the scattered light appears blue. In extremely pure water—as is found in mountain lakes, where scattering from white-colored particles is missing—the scattering from water molecules themselves also contributes a blue color.

The hue of the reflected sky also contributes to the perceived color of water.

Another phenomenon that occurs is Rayleigh scattering in the atmosphere along one's line of sight: the horizon is typically 4–5 km distant and the air (being just above sea level in the case of the ocean) is at its densest. This mechanism would add a blue tinge to any distant object (not just the sea) because blue light would be scattered into one's line of sight.

The surfaces of seas and lakes often reflect blue skylight, making them appear bluer. The relative contribution of reflected skylight and the light scattered back from the depths is strongly dependent on observation angle.[6]

Color of glaciers

Main article: Blue ice (glacial)

Glaciers are large bodies of ice and snow formed during very cold climates by processes involving the compaction of fallen snow. While snowy glaciers appear white from a distance, up close and when shielded from direct ambient light, glaciers usually appear a deep blue due to the long path lengths of the internal reflected light.

Relatively small amounts of regular ice appear white, because plenty of air bubbles are present, and also because small quantities of water appear to be colorless. In glaciers, on the other hand, the pressure causes the air bubbles, trapped in the accumulated snow, to be squeezed out increasing the density of the created ice. As large quantities of water appear to be blue therefore a large piece of compressed ice, or a glacier, would appear blue.

Color of water samples

High concentrations of dissolved lime give the water of Havasu Falls a turquoise color.

Dissolved and particulate material in water can cause discoloration. Slight discoloration is measured in Hazen units (HU).[7] Impurities can be deeply colored as well, for instance dissolved organic compounds called tannins can result in dark brown colors, or algae floating in the water (particles) can impart a green color.

The color of a water sample can be reported as:

Testing for color can be a quick and easy test which often reflects the amount of organic material in the water, although certain inorganic components like iron or manganese can also impart color.

Water color can reveal physical, chemical and bacteriological conditions. In drinking water, green can indicate copper leaching from copper plumbing and can also represent algae growth. Blue can also indicate copper, or might be caused by syphoning of industrial cleaners in the tank of commodes, commonly known as backflowing. Reds can be signs of rust from iron pipes or airborne bacteria from lakes, etc. Black water can indicate growth of sulfur-reducing bacteria inside a hot water tank set to too low a temperature. This usually has a strong sulfur or rotten egg (H2S) odor and is easily corrected by draining the water heater and increasing the temperature to 120 °F (49 °C) or higher. The odor will always be in the hot water pipes if sulfate reducing bacteria are the cause and never in the cold water plumbing. The color spectrum with water indicators is wide and, if learned, can make solving cosmetic, bacteriological and chemical problems easier to identify.

Water quality and color

Glacial rock flour makes New Zealand's Lake Pukaki a lighter turquoise than its neighbors.

The presence of color in water does not necessarily indicate that the water is not drinkable. Color-causing substances such as tannins may be harmless.

Color is not removed by typical water filters; however, slow sand filters can remove color, and the use of coagulants may also succeed in trapping the color-causing compounds within the resulting precipitate.

Other factors can affect the color we see:

Color names

Red tide off the California coast.

Various cultures divide the semantic field of colors differently from the English language usage and some do not distinguish between blue and green in the same way. An example is Welsh where glas can mean blue or green.

Other color names assigned to bodies of water are sea green and ultramarine blue. Unusual oceanic colorings have given rise to the terms red tide and black tide.

The Ancient Greek poet Homer uses the epithet "wine-dark sea"; in addition, he also describes the sea as "grey". Some have suggested that this is due to the Ancient Greeks classifying colors primarily by luminosity rather than hue, while others believe Homer was color-blind.

References

  1. ↑ Davis, Jim; Milligan, Mark (2011), Why is Bear Lake So Blue?, Public Information Series, 96, Utah Geological Survey, p. 10, ISBN 978-1-55791-842-0, retrieved 5 October 2011
  2. 1 2 Braun & Smirnov 1993, p. 612.
  3. ↑ Pope; Fry (1996). "Absorption spectrum (380-700nm) of pure water. II. Integrating cavity measurements". Applied Optics. Bibcode:1997ApOpt..36.8710P. doi:10.1364/ao.36.008710.
  4. ↑ ":"...any simple answer is bound to mislead. It turns out that contributions to the observed color are made both by reflected skylight and by the intrinsic absorption...""Braun CL, Smirnov SN (1993). "Why is Water Blue?" (PDF). J. Chem. Edu. 70 (8): 612. Bibcode:1993JChEd..70..612B. doi:10.1021/ed070p612.
  5. ↑ Rossing, Thomas D.; Chiaverina, Christopher J. (1999), Light science: physics and the visual arts, Springer Science+Business Media, pp. 6–7, ISBN 0-387-98827-0
  6. ↑ "...the relative contribution of reflected skylight and the light scattered back from the depths is strongly dependent on observation angle." Charles L. Braun and Sergei N. Smirnov WHY IS WATER BLUE? J. Chem. Edu., 1993, 70(8), 612 added some sugar too http://www.dartmouth.edu/~etrnsfer/water.htm
  7. ↑ International Organization for Standardization, ISO 2211:1973, Measurement of colour in Hazen units (platinum-cobalt scale) of Liquid Chemical Products

Further reading

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