Tanzanite

Not to be confused with Tasmanite.
Tanzanite

Tanzanite rough stone and cut stone
General
Category Sorosilicate
Formula
(repeating unit)		 (Ca2Al3(SiO4)(Si2O7)O(OH)) + (Cr,Sr)
Strunz classification 09.BG.10
Crystal system Orthorhombic[1]
Identification
Color Blue, Violet
Crystal habit Prismatic crystals with striations; massive to columnar[1][2]
Twinning penetration twins
Cleavage Perfect {010}, imperfect {100}[1]
Fracture Uneven to conchoidal[1]
Mohs scale hardness 6.5
Luster Vitreous, pearly on cleavage surfaces
Streak White or colorless
Specific gravity 3.10–3.38
Optical properties biaxial positive
Refractive index 1.69–1.70
Birefringence 0.006–0.018
Pleochroism Present, dichroism or trichroism depending on heat treatment.

Tanzanite is the blue/violet variety of the mineral zoisite (a calcium aluminium hydroxyl Sorosilicate) belonging to the epidote group. It was discovered by a Tanzanian Jumanne Mhero Ngoma in the Mererani Hills of Manyara Region in Northern Tanzania in 1967, near the city of Arusha and Mount Kilimanjaro. Tanzanite is used as a relatively cheap gemstone, where it can substitute for the far more expensive sapphire after undergoing artificial heat treatment to form a deep blue coloration. Naturally formed tanzanite is extremely rare[3] and is endemic only to the Mererani Hills.[4]

Tanzanite is noted for its remarkably strong trichroism, appearing alternately sapphire blue, violet and burgundy depending on crystal orientation.[5] Tanzanite can also appear differently when viewed under alternate lighting conditions. The blues appear more evident when subjected to fluorescent light and the violet hues can be seen readily when viewed under incandescent illumination. Tanzanite is usually a reddish brown in its rough state, requiring heat treatment to bring out the blue violet of the stone.[6]

The mineral was named by Tiffany & Co. after Tanzania, the country in which it was discovered. In 2002, the American Gem Trade Association chose Tanzanite as a December birthstone, the first change to their birthstone list since 1912.[7]

Commercial history

The craft work on tanzanite.

Manuel d'Souza, a tailor and part-time gold prospector living in Arusha (Tanzania), found transparent fragments of vivid blue and blue-purple gem crystals on a ridge near Mererani, some 40 km (25 mi) southeast of Arusha.[8] He assumed that the mineral was olivine (peridot) but after soon realizing it wasn't, he concluded it was "dumortierite", a blue non-gem mineral. Shortly thereafter, the stones were shown to John Saul, a Nairobi-based consulting geologist and gemstone wholesaler who was then mining aquamarine in the region around Mount Kenya. Saul, with a Ph.D. from M.I.T., who later discovered the famous ruby deposits in the Tsavo area of Kenya, eliminated dumortierite and cordierite as possibilities, and sent samples to his father, Hyman Saul, vice president at Saks Fifth Avenue in New York. Hyman Saul brought the samples across the street to the Gemological Institute of America who correctly identified the new gem as a variety of the mineral zoisite. Correct identification was also made by mineralogists at Harvard University, the British Museum, and Heidelberg University, but the very first person to get the identification right was Ian McCloud, a Tanzanian government geologist based in Dodoma.[9][10]

Scientifically called "blue zoisite", the gemstone was renamed as tanzanite by Tiffany & Co., who wanted to capitalize on the rarity and single location of the gem, and thought that "blue zoisite" (which might be pronounced like "blue suicide") wouldn't sell well.[11] Tiffany's original campaign advertised that tanzanite could now be found in two places: "in Tanzania and at Tiffany's".

From 1967, an estimated two million carats of tanzanite were mined in Tanzania before the mines were nationalized by the Tanzanian government in 1971.

Multicolored Tanzanite Crystal
Untreated Tanzanite Gemstone
Hologram of a Trichroic Tanzanite Specimen
A rough sample of tanzanite.

Recent tanzanite mining developments

In 1990, the Tanzanian government split the Tanzanite mines into four sections: Blocks A, B, C and D. Blocks A and C were awarded to large operators, while Blocks B and D were reserved for the local miners. In 2005 the government renewed the lease of Block C mine to Tanzanite One, who paid 40 million dollars for their lease and mining license.

In June 2003, the Tanzanian government introduced legislation banning the export of unprocessed tanzanite to India (like many gemstones, most tanzanite is cut in Jaipur). The ban has been rationalized as an attempt to spur development of local processing facilities, thereby boosting the economy and recouping profits. This ban was phased in over a two-year period, until which time only stones over 0.5 grams were affected. In 2010, the government of Tanzania banned the export of rough stones weighing more than one gram.[12]

Tanzanite One Mining Ltd is owned by Richland Resources, but a 2010 law in Tanzania required them to cede 50% ownership of their mining license to the Tanzanian State Mining Company (Stamico). Production in 2011 amounted to 2.4 million carats, earning them $24 million.[13]

The world's largest rough tanzanite was a 16,839 carat (3.38 kg, or 7.46 lb) stone mined by TanzaniteOne in 2005.[14]

Factors affecting value: grading

There is no universally accepted method of grading colored gemstones. TanzaniteOne, a major commercial player in the tanzanite market, through its non-profit subsidiary, The Tanzanite Foundation,[15] has introduced its own color-grading system.[16] The new system's color-grading scales divide tanzanite colors into a range of hues, between bluish-violet and violetish-blue.

The normal primary and secondary hues in tanzanite are blue and violet. Untreated tanzanite is a trichroic gemstone, meaning that light that enters this anisotropic crystal gets refracted on different paths, with different color absorption on each of the three optical axes. As a result of this phenomenon, a multitude of colors have been observed in various specimens: shades of purple, violet, blue, cyan, green, yellow, brown and red. After heating, tanzanite becomes dichroic. The dichroic colors range from violet through bluish-violet and violetish-blue to blue.[17]

Clarity grading in colored gemstones is based on the eye-clean standard, that is, a gem is considered flawless if no inclusions are visible with the unaided eye (assuming 20/20 vision).[17] The Gemological Institute of America classifies Tanzanite as a Type I gemstone, meaning it is normally eye-clean. Gems with eye-visible inclusions will be traded at deep discounts.

Heat treatment

Tanzanite forms as a brownish crystal and is trichroic - which means it shows three colors - brown, blue and violet concurrently. Heating - either occurring underground naturally by metamorphic occurrences or above ground by man in a furnace removes the brown or burgundy color component to produce a stronger purplish-blue color and makes the stone "dichroic" which means it only reflects blue and violet.[18] Rarely, gem-quality tanzanite will heat to a green primary hue, most always accompanied by a blue or violet secondary hue. These green tanzanite have some meaningful value in the collector market, but are seldom of interest to commercial buyers.[19]

When heat treated in a furnace, the temperature is usually between 370-390 degrees Celsius for 30 minutes. The stones should not have any cracks or bubbles, as they could shatter or the cracks/ bubble could increase in size during furnace heating.[20]

Some stones found close to the surface in the early days of the discovery (in an area now called D block) were gem-quality blue without the need for heat treatment - probably the result of a wild fire in the area which heated the stones underground. This gave rise to the idea that "D block" stone were more desirable than tanzanite found in other areas of the small tanzanite mining area.

Since heat treatment is universal, it has no effect on price, and finished gems are assumed to be heat-treated. Gemological Institute of America states that the source of heating is gemologically undetectable, but is assumed because of its prevalence.[21]

Tanzanite may be subjected to other forms of treatment as well. Recently, coated Tanzanites were discovered and tested by the AGTA and AGL laboratories.[22] A thin layer containing cobalt, determined by X-ray fluorescence, had been applied to improve the color. It was noted that "coatings in particular are not considered permanent", and in the United States are required to be disclosed at the point of sale.

See also

References

  1. 1 2 3 4 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Zoisite" (PDF). Handbook of Mineralogy. Chantilly, Virginia: Mineralogical Society of America. Retrieved 9 April 2014.
  2. ↑ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1995). Handbook of Mineralogy. 2. Mineral Data Publishing. p. 901. ISBN 978-0-9622097-0-3.
  3. ↑ "Consumers need greater tanzanite exposure". National Jeweler. National Jeweler Network. 30 December 2009. Archived from the original on 31 January 2009. Retrieved 2013-11-26.
  4. ↑ Briggs, Philip; McIntyre, Chris (2013). Tanzania Safari Guide: With Kilimanjaro, Zanzibar and the Coast. Bradt Travel Guides. p. 104. ISBN 978-1-84162-462-4.
  5. ↑ E. Skalwold. "Pleochroism: trichroism and dichroism in gems". Nordskip.com. Retrieved 2011-08-29.
  6. ↑ "YourGemologist / International School of Gemology Study of Heat Treatment". Yourgemologist.com. Retrieved 2011-08-29.
  7. ↑ "AGTA GTC to Issue Tanzanite Reports". JCK Magazine. 12 November 2007. Retrieved 31 December 2013.
  8. ↑ Luhr, James (2003). Earth. New York, NY: DK Publishing, Inc. p. 73. ISBN 0-7894-9643-7.
  9. ↑ "The Mineralogical Record - Merelani, Tanzania".
  10. ↑ "Tanzanite: Its discovery and early days". ICA's InColor Magazine. Summer 2007.
  11. ↑ "Tanzanite". Gemstone.org. Archived from the original on 2008-09-12. Retrieved 2011-08-29.
  12. ↑ "Export ban on tanzanite in Africa leaves Jaipur gems sector in lurch". Times of India. 3 October 2013. Retrieved 31 December 2013.
  13. ↑ Muchira, John (24 May 2013). "TanzaniteOne cedes 50% stake to State as new law takes effect". Mining Weekly.
  14. ↑ Cobley, Mark (3 August 2005). "World's Biggest Tanzanite Gem Found Near Kilimanjaro (Update3)". Bloomberg. Retrieved 31 December 2013.
  15. ↑ "The Tanzanite Foundation". The Tanzanite Foundation. 2013-04-22. Retrieved 2013-11-26.
  16. ↑ Roskin, Gary (May 2005). Tanzanite "Tanzanite Transformed: TanzaniteOne Introduces Quality Grading, Pricing Changes, and a Sight System" Check |url= value (help). JCK Magazine. Retrieved 31 December 2013.
  17. 1 2 Richard W. Wise (31 December 2005). Secrets of the Gem Trade: The Connoisseur's Guide to Precious Gemstones. Brunswick House Press. pp. 35,220. ISBN 978-0-9728223-8-1.
  18. ↑ Weldon, Robert. "An introduction to gem treatments". Gemological Institute of America, Inc.
  19. ↑ Tanzanite Gemological Information
  20. ↑ Roskin, Gary (February 2005). "Natural-Color Tanzanite". JCK Magazine.
  21. ↑ GIA On Tanzanite 1999 "Featured gemstone: tanzanite" Check |archiveurl= value (help). GIA Library. Gemological Institute of America, Inc. Archived from the original on 13 May 2008.
  22. ↑ Gemmological Association of Great Britain; German Gemmological Association; Netherlands Gemmological Laboratory (25 May 2008). "Coatings: a new Tanzanite treatment uncovered". Farlang's Gem and Diamond Foundation.
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